MOLYBDENUM(VI) CATALYSIS OF PERBORATE OR HYDROGEN-PEROXIDE OXIDATION OF IODIDE-ION

被引：46

作者：

KARUNAKARAN, C

MUTHUKUMARAN, B

机构：

[1] Department of Chemistry, Annamalai University, Annamalainagar

来源：

TRANSITION METAL CHEMISTRY | 1995年 / 20卷 / 05期

关键词：

D O I：

10.1007/BF00141517

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perborate in aqueous solution generates H2O2; in its presence the molybdenum(VI) catalysed oxidation of iodide ion is first order with respect to the oxidant and catalyst, and is independent of [I-] and [H+]. Kinetic studies point to peroxymolybdenum(VI) species as the oxidizing species.

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页码：460 / 462

页数：3

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