PREPARATION OF GRAPHITE-LIKE POLYMERS FROM 1,3-DIACETYLENES - PYROLYTIC POLY[1-(2-METHOXYPHENYL)PENTA-1,3-DIYN-5-OL]

被引：15

作者：

LEE, HJ

SUH, MC

SHIM, SC

机构：

[1] Department of Chemistry, Korea Advanced Institute of Science and Technology, Taejon, 305-701, 373-1 Kusong-Dong, Yusong-Ku

来源：

SYNTHETIC METALS | 1995年 / 71卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)03041-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly[1-(2-methoxyphenyl)penta-1,3-diyn-5-ol] [(1,2)-PMDO] was prepared by NbCl5/(n-Bu)(4)Sn catalyzed metathesis of (1,2)MDO followed by spin-casting in methylene chloride. Thin films of resulting polymers were pyrolyzed at various temperatures. UV, IR, and Raman spectroscopic studies were carried out to determine the chemical structure of the films during pyrolysis. The electrical conductivity of the films could be varied on cabonization at different temperatures.

引用

页码：1763 / 1764

页数：2

共 4 条

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