ATMOSPHERIC IMPLICATIONS OF THE PHOTOLYSIS OF THE OZONE-WATER WEAKLY-BOUND COMPLEX

被引：99

作者：

FROST, G

VAIDA, V

机构：

[1] UNIV COLORADO, DEPT CHEM & BIOCHEM, BOULDER, CO 80309 USA

[2] NOAA, AERON LAB, BOULDER, CO 80303 USA

来源：

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES | 1995年 / 100卷 / D9期

关键词：

D O I：

10.1029/95JD01940

中图分类号：

P4 [大气科学（气象学）];

学科分类号：

0706 ; 070601 ;

摘要：

The atmospheric rate of photolysis of the ozone-water weakly bound complex, O-3 . H2O, is evaluated. On the basis of this information, we discuss the potential role of this chemistry in the production of OH in the troposphere. While there are uncertainties inherent in the experimental database available for O-3 . H2O, the calculations show that photolysis of this complex is a potentially significant tropospheric OH source.

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页码：18803 / 18809

页数：7

相关论文

共 33 条

[1] THE KINETICS AND MECHANISM OF HYDROXIDE ION CATALYZED OZONE DECOMPOSITION IN AQUEOUS SOLUTION [J].

ALDER, MG ;

HILL, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (05) :1884-1886

[2]

[Anonymous], 1986, AERONOMY MIDDLE ATMO

[3] MEASUREMENT OF THE PERPENDICULAR ROTATION-TUNNELING SPECTRUM OF THE WATER DIMER BY TUNABLE FAR INFRARED-LASER SPECTROSCOPY IN A PLANAR SUPERSONIC JET [J].

BUSAROW, KL ;

COHEN, RC ;

BLAKE, GA ;

LAUGHLIN, KB ;

LEE, YT ;

SAYKALLY, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (08) :3937-3943

[4] STUDIES OF MOLECULAR ASSOCIATION IN H2O AND D2O VAPORS BY MEASUREMENT OF THERMAL-CONDUCTIVITY [J].

CURTISS, LA ;

FRURIP, DJ ;

BLANDER, M .

JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (06) :2703-2711

[5] THERMODYNAMIC PROPERTIES OF GAS-PHASE HYDROGEN-BONDED COMPLEXES [J].

CURTISS, LA ;

BLANDER, M .

CHEMICAL REVIEWS, 1988, 88 (06) :827-841

[6]

DEMORE WB, 1994, JPL9426 NASA JET PRO

[7] SPECTROSCOPY OF THE N0-3S RYDBERG STATE OF ISOLATED AND CLUSTERED ACETALDEHYDE [J].

DONALDSON, DJ ;

RICHARD, EC ;

STRICKLER, SJ ;

VAIDA, V .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (19) :5514-5517

[8] ULTRAVIOLET-ABSORPTION SPECTROSCOPY OF DISSOCIATING MOLECULES - EFFECTS OF CLUSTER FORMATION ON THE PHOTODISSOCIATION OF CH3I [J].

DONALDSON, DJ ;

VAIDA, V ;

NAAMAN, R .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (05) :2522-2530

[9] ULTRAVIOLET-ABSORPTION DETERMINATION OF INTRAMOLECULAR PREDISSOCIATION DYNAMICS IN (CH3I)2 AND (CD3I)2 [J].

DONALDSON, DJ ;

VAIDA, V ;

NAAMAN, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (05) :1204-1208

[10] CLUSTER-INDUCED POTENTIAL SHIFTS AS A PROBE FOR DISSOCIATION DYNAMICS IN THE N-3S RYDBERG STATE OF ACETONE [J].

DONALDSON, DJ ;

GAINES, GA ;

VAIDA, V .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (10) :2766-2769

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