SYNTHESIS AND DIELS-ALDER REACTIONS OF TERT-BUTYL AND TERT-BUTYL, METHYL (S)S-2-PARA-TOLYLSULFINYLMALEATES, CHIRAL SYNTHETIC EQUIVALENTS OF MONOALKYL AND MIXED DIALKYL ACETYLENEDICARBOXYLATES

被引：15

作者：

ALONSO, I ^{[1
]}

CARRETERO, JC ^{[1
]}

RUANO, JLG ^{[1
]}

机构：

[1] UNIV AUTONOMA MADRID,DEPT QUIM C-I,CANTOBLANCO,E-28049 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)92127-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of t-butyl p-tolylsulfinylacetate with glyoxylic acid yielded maleate monoester 1, whose methylation afforded asymmetric diester 2. Conditions in which 1 and 2 react with cyclopentadiene exhibiting high facial and endo selectivities are reported.

引用

页码：947 / 950

页数：4

共 15 条

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