TRIS(TERT-BUTOXO)SILYLTHIOLATO COMPLEXES OF VANADIUM(V, IV, III)

被引：15

作者：

PREUSS, F

STEIDEL, M

EXNER, R

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1990年 / 45卷 / 12期

关键词：

TRIS(TERT-BUTOXO)SILYLTHIOLATO COMPLEXES OF VANADIUM(V; IV; III); PREPARATION; NMR SPECTRA; ESR SPECTRA; X-RAY STRUCTURE DETERMINATION;

D O I：

10.1515/znb-1990-1204

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes (t)C4H9N = V(O(t)C4H9)3-n[SSi(O(t)C4H9)3]n, O = V(O(t)C4H9)3-n[SSi(O(t)C4H9)3]n, O = V[SSi(O(t)C4H9)3]2 (9) and VCl[SSi(O(t)C4H9)3]2 have been prepared by reaction of chlorovanadium compounds with LiSSi(O(t)C4H9)3. All complexes are characterized by NMR (H-1, V-51) and ESR spectroscopy. 9 has been found by X-ray diffraction analysis to be a distorted trigonal bipyramidal complex with bidentate thiolate ligands.

引用

页码：1618 / 1624

页数：7

共 19 条

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