PD(O) AND NI(O) CATALYZED POLYMERIZATION REACTIONS

被引：23

作者：

PERCEC, V ^{[1
]}

PUGH, C ^{[1
]}

CRAMER, E ^{[1
]}

OKITA, S ^{[1
]}

WEISS, R ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 54-5卷

关键词：

D O I：

10.1002/masy.19920540113

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Three novel metal catalyzed cross-coupling polymerization reactions which result in carbon-carbon bond formation are described and discussed in context with other metal catalyzed cross-coupling polymerization reactions. Diarylacetylene monomers and dimers are prepared by the phase transfer Pd(0)/Cu(I) catalyzed coupling of aryl halides with 2-methyl-3-butyn-2-ol. Aryl-alkyl bond forming polymerization reactions are achieved by the phase transfer Pd(0) catalyzed coupling of B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with aryl halides. Soluble polyphenylenes are prepared by the Ni(0) catalyzed homocoupling of substituted phenylenebistriflates in the presence of zinc.

引用

页码：113 / 150

页数：38

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