[(METHYLDIPHENYLPHOSPHONIO)METHANIDE]TRIS(PENTAFLUOROPHENYL)GOLD(III) ACETONE SOLVATE

被引：2

作者：

JONES, PG

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191013914

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Au(C14H15P)(C18F15)].C3H6O, M(r) = 970.45, triclinic, P1BAR, a = 11.258 (3), b = 13.586 (3), c = 13.969 (3) angstrom, alpha = 108.77 (2), beta = 101.69 (2), gamma = 112.07 (1)-degrees, V = 1742 (1) angstrom3, Z = 2, D(x) = 1.850 Mg m-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 4.4 mm-1, F(000) = 936, T = 293 K, R = 0.036 for 6980 reflections. The coordination at the Au atom is square planar, with Au-C(ylide) 2.109 (6), Au-C6F5 2.055-2.069 (4-6) angstrom and P-C(ylide) 1.773 (6) angstrom. No trans effect is observed.

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页码：1209 / 1211

页数：3

相关论文

共 13 条

[1] THE DISTORTION OF PENTAFLUOROPHENYL GROUPS IN METAL-COMPLEXES - LIMITATIONS OF RIGID-BODY REFINEMENT [J].

JONES, PG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 345 (03) :405-411

[2] BIS(DIPHENYLPHOSPHINO)METHANIDE OR BIS(DIPHENYLPHOSPHINO)METHAMIDE AND ITS DERIVATIVES AS LIGANDS IN GOLD CHEMISTRY - A REVIEW [J].

LAGUNA, A ;

LAGUNA, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 394 (1-3) :743-756

[3] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF [AU(CH2)2PPH2]2(CF3)2, [AU(CH2)2PPH2]2(C6F5)2, AND [PPN][AU(C6F5)4] - 2 DINUCLEAR GOLD(II) YLIDE COMPLEXES CONTAINING ALKYL AND ARYL LIGANDS AND A TETRAKIS(PENTAFLUOROPHENYL)AURATE(III) ANION COMPLEX [J].

MURRAY, HH ;

FACKLER, JP ;

PORTER, LC ;

BRIGGS, DA ;

GUERRA, MA ;

LAGOW, RJ .

INORGANIC CHEMISTRY, 1987, 26 (03) :357-363

[4]

SHELDRICK GM, 1987, SHELXTL PLUS RELEASE

[5] STRUCTURE AND PROPERTIES OF TRANSITION-METAL YLIDE COMPLEXES .2. ORGANOMETALLIC COMPLEXES OF GOLD(III) [J].

STEIN, J ;

FACKLER, JP ;

PAPARIZOS, C ;

CHEN, HW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) :2192-2198

[6] A NEW ROUTE FOR THE SYNTHESIS OF GOLD(I) AND GOLD(III) PENTAFLUOROPHENYL(YLIDE) COMPLEXES [J].

USON, R ;

LAGUNA, A ;

LAGUNA, M ;

USON, A .

INORGANICA CHIMICA ACTA-ARTICLES, 1983, 73 (01) :63-66

[7] NOVEL PHOSPHORUS YLIDE TRANSFER-REACTIONS FROM GOLD(I) TO GOLD(I) OR FROM GOLD(I) TO GOLD(III) CENTERS [J].

USON, R ;

LAGUNA, A ;

LAGUNA, M ;

USON, A ;

GIMENO, MC .

ORGANOMETALLICS, 1987, 6 (03) :682-683

[8] MONO-NUCLEAR, BI-NUCLEAR, AND TRI-NUCLEAR BIS(DIPHENYLPHOSPHINO)METHANE GOLD COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF [BIS(DIPHENYLPHOSPHINO)METHANE]BIS(PENTAFLUOROPHENYL)GOLD(III) PERCHLORATE AND 1,2-2,3-DI-MU-[BIS(DIPHENYLPHOSPHINO)METHANE]-1,3-DICHLOROTRIGOLD(I) CHLOROTRIS(PENTAFLUOROPHENYL)AURATE(III)PH [J].

USON, R ;

LAGUNA, A ;

LAGUNA, M ;

FERNANDEZ, E ;

VILLACAMPA, MD ;

JONES, PG ;

SHELDRICK, GM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08) :1679-1685

[9] RECENT DEVELOPMENTS IN ARYLGOLD CHEMISTRY [J].

USON, R ;

LAGUNA, A .

COORDINATION CHEMISTRY REVIEWS, 1986, 70 :1-50

[10] BIMETALLIC PHOSPHORUS YLIDE GOLD-SILVER COMPLEXES [J].

USON, R ;

LAGUNA, A ;

LAGUNA, M ;

USON, A ;

JONES, PG ;

ERDBRUGGER, CF .

ORGANOMETALLICS, 1987, 6 (08) :1778-1780