ORGANIC-INORGANIC SALTS MADE BY TTF AND MAGNETIC CLUSTERS

被引：13

作者：

GOMEZGARCIA, CJ

BORRASALMENAR, JJ

CORONADO, E

DELHAES, P

GARRIGOULAGRANGE, C

BAKER, LCW

机构：

[1] CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE

[2] GEORGETOWN UNIV,DEPT CHEM,WASHINGTON,DC

来源：

SYNTHETIC METALS | 1993年 / 56卷 / 01期

关键词：

ION-RADICAL SALTS; TTF; MAGNETIC MATERIALS; HIGH SPIN CLUSTERS; POLYOXOMETALATES;

D O I：

10.1016/0379-6779(93)90366-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We present a first report of the now organic-inorganic salts formed by the organic donor TTF and the inorganic clusters [Co4(H2O)2(PW9O34)2]-10 and [Cr(OH)6Mo6O18]-3. We show that these metal oxide anions can be used successfully as magnetic components of radical ion salts based on TTF-type radicals. On the other hand, the magnetic features of these salts provide some evidence of the presence of substantial interactions between the two components.

引用

页码：2023 / 2027

页数：5

共 5 条

[1] TRIVACANT HETEROPOLYTUNGSTATE DERIVATIVES .3. RATIONAL SYNTHESES, CHARACTERIZATION, TWO-DIMENSIONAL W-183 NMR, AND PROPERTIES OF P2W18M4(H2O)2O68(10-) AND P4W30M4(H2O)2O112(16-)(M = CO, CU, ZN) [J].