SOLVENT CAGE SPECTROSCOPY

被引：13

作者：

KASHA, M ^{[1
]}

SYTNIK, A ^{[1
]}

DELLINGER, B ^{[1
]}

机构：

[1] FLORIDA STATE UNIV,DEPT CHEM,TALLAHASSEE,FL 32306

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 08期

关键词：

D O I：

10.1351/pac199365081641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potential functions for photodissociation, excited state intramolecular torsion, and excited state twisting-intramolecular-charge-transfer are discussed in terms of sensitivity to solvent cage perturbation. A spectroscopic solvent cage theory based on a Born-Oppenheimer quantum mechanical framework is used for the justification of adducing viscous flow barriers as perturbations to the intrinsic molecular potentials. Experimental correlation of new spectroscopic phenomena is presented for each of the three potentials under perturbation.

引用

页码：1641 / 1646

页数：6

共 27 条

[1] THE VISCOSITY DEPENDENCE AND REACTION COORDINATE FOR ISOMERIZATION OF CIS-STILBENE [J].