THE SYNTHESIS AND CHARACTERIZATION OF RU(6)(MU(3)-H)(MU(4)-ETA(2)-CO)(2)(CO)(13)(ETA(5)-C(5)H(4)ME) - AN EXAMPLE OF CLUSTER MEDIATED RING CONTRACTION

被引：18

作者：

INGHAM, SL

JOHNSON, BFG

MARTIN, CM

PARKER, D

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] ICI GRP R&T AFFAIRS,MIDDLESBROUGH TS90 8JE,CLEVELAND,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000159

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of cyclohexene with Ru-3(CO)(12) leads primarily to dehydrogenation with products based on C6H8 and C6H6. however the formation of the cluster complex RU(6)(mu(3)-H)(mu(4)-eta(2)-CO)(2)(CO)(13)(eta(5)-C(5)H(4)Me) 1, has revealed that C-C activation and ring contraction is also a significant reaction pathway.

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页码：159 / 160

页数：2

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