INDENE IN A NOVEL BONDING MODE IN A CARBONYL CLUSTER - ISOLATION, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR-STRUCTURE OF [HOS4(CO)9(C9H6)(C9H7)]

被引：8

作者：

CHEN, H

FAJARDO, M

JOHNSON, BFG

LEWIS, J

RAITHBY, PR

机构：

[1] University Chemical Laboratory, Cambridge, CB2 1EW, Lensfield Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 389卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85402-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Os3(CO)12] with indene at 150°C under reflux affords the known compounds [H2Os3(CO)9(C9H6)] (2) and [Os4(CO)12(C9H6)] (3). When the reaction temperature is increased to 170°C, the yield of 2 is greatly reduced, and a new tetraosmium cluster [HOs4(CO)9(C9H6)(C9H7)] (1) is isolated. An X-ray diffraction study of 1 has shown that one face of the Os4 tetrahedron is capped by an indyne ligand coordinated in a μ3-η2-- bonding mode, while the indenyl ligand (C9H7) is coordinated to a single Os atom in a η5 bonding mode through the five-membered ring. © 1990.

引用

收藏

页码：C16 / C18

页数：3

相关论文

共 10 条

[1]

BROACH RW, 1979, INORG CHEM, V18, P314, DOI 10.1021/ic50192a021

[2] SYNTHESIS, STRUCTURES, AND SOLUTION DYNAMICS OF MONONUCLEAR AND DINUCLEAR (ETA-5-INDENYL)RHODIUM COMPLEXES OF OCTAFLUOROCYCLOOCTATETRAENE - CRYSTAL AND MOLECULAR-STRUCTURES OF [RH(ETA-5-C9H7)(1,2,5,6-ETA-C8F8)], ([RH(ETA-5-C9H7)]2[MU-(1,5,6-ETA-2-4-ETA-C8F8)](RH-RH)), ([RH(ETA-5-C9H7)]2[MU-(1,5,6-ETA-2-4-ETA-C8F7H)](RH-RH)), AND ([RH(ETA-5-C9H7)(CO)][RH(ETA-5-C9H7)][MU-(1,2,5,6-ETA-7,8-ETA-C8F8])] [J].

CARL, RT ;

HUGHES, RP ;

RHEINGOLD, AL ;

MARDER, TB ;

TAYLOR, NJ .

ORGANOMETALLICS, 1988, 7 (07) :1613-1624

[3] SYNTHESIS AND CHARACTERIZATION OF ETA-6-CR(CO)3-INDENYL-ETA-3-RHODIUM-ETA-4-C8H12 - AN ETA-3-ETA-6 COORDINATION FOR THE INDENYL LIGAND [J].

CECCON, A ;

GAMBARO, A ;

SANTI, S ;

VALLE, G ;

VENZO, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) :51-53

[4] ISOLATION AND X-RAY STRUCTURE DETERMINATION OF [OS4(CO)12(C9H6)], AN INDYNE BUTTERFLY CLUSTER [J].

CHEN, H ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (05) :373-374

[5] SOME STUDIES ON A MU-3-INDYNE COMPLEX OF TRIOSMIUM RELATING TO ALKYNE ROTATION IN M3C2 CLUSTERS [J].

DEEMING, AJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 150 (01) :123-128

[6] DODECACARBONYLTETRA-MU-HYDRIDO-TETRAHEDRO-TETRAOSMIUM [J].

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR ;

ZUCCARO, C .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (SEP) :1728-1731

[7] THE HAPTICITY OF ETA-INDENYL COMPLEXES - MOLECULAR-STRUCTURES OF [(ETA-5-C9R7)RH(ETA-4-COD)] (R = H, ME) (COD = CYCLO-OCTA-5-DIENE) [J].

KAKKAR, AK ;

JONES, SF ;

TAYLOR, NJ ;

COLLINS, S ;

MARDER, TB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) :1454-1456

[8] AN UNUSUAL ROTATIONAL DISTORTION IN AN [(ETA-INDENYL)RHL2] COMPLEX - MOLECULAR-STRUCTURES OF [(ETA-1,2,3-ME3C9H4)RH(ETA-C2H4)2] AND [(ETA-C9H7)RH(CO)2] [J].

KAKKAR, AK ;

TAYLOR, NJ ;

CALABRESE, JC ;

NUGENT, WA ;

ROE, DC ;

CONNAWAY, EA ;

MARDER, TB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (15) :990-992

[9] SYNTHESIS AND STRUCTURE OF THE [RH2(DMPE)4(MU-DMPE)]2+ SALT OF THE NAKED CYCLOPENTADIENYL ANION - A COMPARISON OF THE REACTIVITY OF [(ETA-INDENYL)RH(ETA-C2H4)2] AND [(ETA-C5H5)RH(ETA-C2H4)2] [J].

KAKKAR, AK ;

TAYLOR, NJ ;

MARDER, TB .

ORGANOMETALLICS, 1989, 8 (07) :1765-1768

[10] ALKYNE-SUBSTITUTED TRANSITION-METAL CLUSTERS [J].

RAITHBY, PR ;

ROSALES, MJ .

ADVANCES IN INORGANIC CHEMISTRY, 1985, 29 :169-247