NEW POLYCARBOSILANE MODELS .2. 1ST SYNTHESIS OF POLYSILAPROPYLENE

被引：47

作者：

BACQUE, E ^{[1
]}

PILLOT, JP ^{[1
]}

BIROT, M ^{[1
]}

DUNOGUES, J ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CNRS,UNITE 35,CHIM ORGAN & ORGANOMET LAB,351 COURS LIBERAT,F-33405 TALENCE,FRANCE

来源：

MACROMOLECULES | 1988年 / 21卷 / 01期

关键词：

LITHIUM COMPOUNDS - NUCLEAR MAGNETIC RESONANCE - SILANES;

D O I：

10.1021/ma00179a008

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Linear polycarbosilanes containing (methyl- and methyldeuteriosilylene)methylene units were synthesized for the first time and characterized by **1H, **1**3C, and **2**9Si NMR. These polymers provide convenient models for studying both configurational sequence effects and Yajima's thermal polydimethylsilane-polycarbosilane rearrangement. Their terminal reticulation was investigated and the main gas evolved characterized.

引用

页码：34 / 38

页数：5

共 12 条

[1] NEW POLYCARBOSILANE MODELS .1. POLY[(METHYLCHLOROSILYLENE)METHYLENE], A NOVEL, FUNCTIONAL POLYCARBOSILANE
BACQUE, E
PILLOT, JP
BIROT, M
DUNOGUES, J
[J]. MACROMOLECULES, 1988, 21 (01) : 30 - 34
[2] STUDY OF THE POLYDIMETHYLSILANE-POLYCARBOSILANE TRANSFORMATION .1. ANALYSIS OF RELEASED GASES
BIROT, M
BACQUE, E
PILLOT, JP
DUNOGUES, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 319 (03) : C41 - C44
[3] NUCLEOPHILIC DISPLACEMENT AT SILICON - RECENT DEVELOPMENTS AND MECHANISTIC IMPLICATIONS
CORRIU, RJP
GUERIN, C
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1982, 20 : 265 - 312
[4] SILICON-SILICON BOND DISSOCIATION ENERGY IN HEXAMETHYLDISILANE
DAVIDSON, IM
STEPHENS.IL
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (02): : 282 - &
[5] EABORN C, 1960, ORGANOSILICON COMPOU, P194
[6] SYNTHESIS OF CONTINUOUS SILICON-CARBIDE FIBER .3. PYROLYSIS PROCESS OF POLYCARBOSILANE AND STRUCTURE OF THE PRODUCTS
HASEGAWA, Y
OKAMURA, K
[J]. JOURNAL OF MATERIALS SCIENCE, 1983, 18 (12) : 3633 - 3648
[7] SYNTHESIS OF CONTINUOUS SILICON-CARBIDE FIBER .4. THE STRUCTURE OF POLYCARBOSILANE AS THE PRECURSOR
HASEGAWA, Y
OKAMURA, K
[J]. JOURNAL OF MATERIALS SCIENCE, 1986, 21 (01) : 321 - 328
[8] THERMAL REARRANGEMENT OF HEXAMETHYLDISILANE TO TRIMETHYL(DIMETHYLSILYLMETHYL)-SILANE
SHIINA, K
KUMADA, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (01) : 139 - 139
[9] SHILLING CL, 1983, AM CERAM SOC B, V8, P912
[10] WIBERG E, 1971, HYDRIDES ELEMENTS MA, P381

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