CHEMISTRY OF PDII COMPLEXES CONTAINING BOTH BINAP (2'2'-BIS(DIPHENYLPHOSPHINO)BINAPHTHYL) AND A ETA-3-PINENE OR ETA-3-ALLYL LIGAND - NMR-STUDIES ON [PD(ETA-3-C10H15)(S(-)BINAP)] (CF3SO3) - THE CRYSTAL-STRUCTURE OF [PD(ETA-3-C10H15)(4,4'-DIMETHYLBIPYRIDINE)](CF3SO3)

被引：47

作者：

AMMANN, CJ

PREGOSIN, PS

RUEGGER, H

ALBINATI, A

LIANZA, F

KUNZ, RW

机构：

[1] SWISS FED INST TECHNOL,ANORGAN CHEM LAB,UNIVERSITATSTR 6,CH-8092 ZURICH,SWITZERLAND

[2] UNIV MILAN,IST CHIM FARMACEUT,I-20131 MILAN,ITALY

[3] UNIV ZURICH,INST ORGAN CHEM,CH-8057 ZURICH,SWITZERLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 423卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83135-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One and two-dimensional H-1, C-13 and P-31 NMR studies on palladium(II) complexes containing eta-(3)-C10H15 or eta(3)-C4H7 allyl and S(-)BINAP ligands are reported. Details of the three-dimensional solution structure for [Pd(eta(3)-C10H15){S(-)BINAP}](CF3SO3) based on H-1-2D NOESY and molecular modeling calculations are presented. The structure for the model beta-pinene allyl complex [Pd(eta(3)-C10H15)(4,4'-dimethylbipyridine)](CF3SO3) has been determined by an X-ray diffraction study, which reveals that the CH2 terminal allyl carbon is significantly displaced from the N-Pd-N plane.

引用

页码：415 / 430

页数：16

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