A KINETIC-MODEL OF STEP-WISE ALTERNATING POLYMERIZATION FOR 2 BI-FUNCTIONAL MONOMERS

被引:4
作者
GALINA, H
机构
[1] Department of Industrial and Materials Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Rzeszow, 35-959, ul. W. Pola 2,
关键词
D O I
10.1002/mats.1995.040040413
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A classical kinetic model of step-wise alternating copolymerization is presented. A set of three partial differential equations is derived for generating functions describing the size distribution of molecules terminated with two different or two alike units. From monomer composition and reactivities of functional groups the moments or averages of the molecular size distribution of copolymers can be calculated.
引用
收藏
页码:801 / 809
页数:9
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