ENANTIOSELECTIVE ISOTACTIC ALTERNATING COPOLYMERIZATION OF STYRENE AND 4-METHYLSTYRENE WITH CARBON-MONOXIDE CATALYZED BY A CATIONIC BIOXAZOLINE PD(II) COMPLEX

被引：106

作者：

BARTOLINI, S

CARFAGNA, C

MUSCO, A

机构：

[1] Istituto di Scienze Chimiche, Universitá Degli Studi Diurbino, Urbino

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1995年 / 16卷 / 01期

关键词：

D O I：

10.1002/marc.1995.030160102

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The cationic bioxazoline Pd(II) complex 2 catalyzes the alternating copolymerization of carbon monoxide with styrene and 4-methylstyrene, respectively, to yield a highly isotactic optically active polymer at room temperature and low carbon monoxide pressure (1-4 atm).

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页码：9 / 14

页数：6

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