NEAR-INFRARED-EXCITED FT-RAMAN SPECTRA OF COVALENTLY LINKED PORPHYRIN NITROBENZENE COMPOUNDS

被引：17

作者：

AKINS, DL

GUO, C

ZHU, HR

机构：

[1] Department of Chemistry, City College of the City University of New York, New York

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 16期

关键词：

D O I：

10.1021/j100118a008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

FT-Raman spectra for three covalently linked porphyrin-nitrobenzene compounds have been acquired using near-infrared (1064 nm) excitation. The relative intensities of several Raman bands are found to depend on the substitution pattern of the porphyrin macrocycle and on whether the covalent linkage is through single or double bonds. Spectra are interpreted as indicating that ground-state electronic coupling between the porphyrin and nitrobenzene moieties occurs by way of a through-bond mechanism.

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页码：3974 / 3977

页数：4

相关论文

共 41 条

[1] RESONANCE RAMAN-SPECTRA OF OCTAETHYLPORPHYRINATO-NI(II) AND MESO-DEUTERATED AND N-15 SUBSTITUTED DERIVATIVES .2. NORMAL COORDINATE ANALYSIS [J].

ABE, M ;

KITAGAWA, T ;

KYOGOKU, Y .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (10) :4526-4534

[2] RESONANCE RAMAN-SPECTROSCOPY OF EXCITED-STATE IRON(III) TETRAPHENYLPORPHYRIN [J].

AUSTIN, JC ;

BELL, SEJ ;

HESTER, RE .

CHEMICAL PHYSICS LETTERS, 1990, 169 (04) :342-346

[3] CHLOROPHYLL MODEL COMPOUNDS - EFFECTS OF LOW SYMMETRY ON THE RESONANCE RAMAN-SPECTRA AND NORMAL MODE DESCRIPTIONS OF NICKEL(II) DIHYDROPORPHYRINS [J].

BOLDT, NJ ;

DONOHOE, RJ ;

BIRGE, RR ;

BOCIAN, DF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (08) :2284-2298

[4] FOURIER-TRANSFORM RAMAN-SPECTROSCOPY [J].

CHASE, B .

ANALYTICAL CHEMISTRY, 1987, 59 (14) :A881-&

[5] FOURIER-TRANSFORM RAMAN-SPECTROSCOPY [J].

CHASE, DB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) :7485-7488

[6]

Connolly J.S., 1988, PHOTOINDUCED ELECT D, P303

[7]

COWEN JA, 1987, J CHEM SOC CHEM COMM, P55

[8] TRANSIENT RAMAN DIFFERENCE SPECTROSCOPY OF NICKEL(II) UROPORPHYRIN PI-PI-COMPLEXES [J].

CRAWFORD, BA ;

ONDRIAS, MR ;

SHELNUTT, JA .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (17) :6647-6652

[9] RESONANCE RAMAN-SPECTROSCOPY REVEALS A1U VS A2U CHARACTER AND PSEUDO-JAHN-TELLER DISTORTION IN RADICAL CATIONS OF NIII, CUII, AND CLFEIII OCTAETHYLPORPHYRINS AND TETRAPHENYLPORPHYRINS [J].

CZERNUSZEWICZ, RS ;

MACOR, KA ;

LI, XY ;

KINCAID, JR ;

SPIRO, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) :3860-3869

[10] RESONANCE RAMAN-SPECTRA AND NORMAL MODE DESCRIPTIONS OF A BACTERIOCHLOROPHYLL-A MODEL COMPLEX [J].

DONOHOE, RJ ;

FRANK, HA ;

BOCIAN, DF .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1988, 48 (04) :531-537

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