THE TANDEM INTRAMOLECULAR DIELS-ALDER REACTION

被引：13

作者：

GOLDBERG, DR ^{[1
]}

HANSEN, JA ^{[1
]}

GIGUERE, RJ ^{[1
]}

机构：

[1] SKIDMORE COLL,DEPT CHEM,SARATOGA SPRINGS,NY 12866

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)61435-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The tandem intramolecular Diels-Alder (TIMDA) reaction of ketone 3 is reported. The reaction proceeds under mild conditions (BF3.Et(2)0, 0 degrees C) and affords two tetracyclic products diastereoselectively. TIMDA substrate 3 is prepared in a convergent manner from 1,5-pentanediol.

引用

页码：8003 / 8006

页数：4

共 35 条

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