SPECTROSCOPIC STUDY OF SOL-GEL SILICA DOPED WITH IRON IONS

被引:37
作者
LOPEZ, T
MENDEZ, J
ZAMUDIO, T
VILLA, M
机构
[1] Universidad Autónoma Metropolitana, Depto. de Química, Iztapalapa
关键词
D O I
10.1016/0254-0584(92)90218-W
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silicas doped with different amounts of iron are prepared by the sol-gel method. The solids received different thermal treatments. UV-VIS and IR spectra are analyzed in order to study the Fe(III) complexes formed in the silica network and deposited on the solid surface. At 300-degrees-C the humidity water and the solvent are evaporated. At 600-degrees-C the water coordinated to the Fe(III) is eliminated, causing a structural rearrangement of the silica.
引用
收藏
页码:161 / 167
页数:7
相关论文
共 31 条
[1]   ELECTRONIC STRUCTURES OF HEXACYANOMETALATE COMPLEXES [J].
ALEXANDER, JJ ;
GRAY, HB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (16) :4260-+
[2]   EFFECT OF HYDROLYTIC POLYCONDENSATION OF TETRAETHOXYSILANE ON SPECIFIC SURFACE-AREA OF SIO2 GELS [J].
BOONSTRA, AH ;
MULDER, CAM .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 105 (03) :201-206
[3]   STRUCTURAL EVOLUTION DURING THE GEL TO GLASS CONVERSION [J].
BRINKER, CJ ;
ROTH, EP ;
SCHERER, GW ;
TALLANT, DR .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1985, 71 (1-3) :171-185
[4]   HYDROLYSIS AND CONDENSATION OF SILICATES - EFFECTS ON STRUCTURE [J].
BRINKER, CJ .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 100 (1-3) :31-50
[5]   CHARGE-TRANSFER AND INTRALIGAND ELECTRONIC SPECTRA OF BIPYRIDYL COMPLEXES OF IRON, RUTHENIUM, AND OSMIUM .2. TERVALENT COMPLEXES [J].
BRYANT, GM ;
FERGUSSO.JE .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1971, 24 (02) :275-&
[6]   BONDING STUDIES FROM CHARGE-TRANSFER ABSORPTION AND MAGNETIC CIRCULAR-DICHROISM SPECTRA .2. COMPLEX HEXACYANOFERRATE (III) AND PENTACYANOFERRATE(III) COMPLEXES OF C4V SYMMETRY [J].
GALE, R ;
MCCAFFERY, AJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (13) :1344-1351
[7]   BAND LIMITS AND THE VIBRATIONAL-SPECTRA OF TETRAHEDRAL GLASSES [J].
GALEENER, FL .
PHYSICAL REVIEW B, 1979, 19 (08) :4292-4297
[8]  
GALEENER FL, 1982, STRUCTURE NONCRYSTAL, P337
[9]   GEL-GLASS TRANSFORMATION IN THE SIO2-FE2O3 SYSTEM [J].
GUGLIELMI, M ;
PRINCIPI, G .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1982, 48 (01) :161-175
[10]   ELECTRONIC AND VIBRATIONAL-SPECTRA OF FERRICYANIDE IONS DOPED IN NACL AND KCL CRYSTALS [J].
JAIN, SC ;
WARRIER, AVR ;
SEHGAL, HK .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1973, 6 (01) :193-200