THERMAL DEHYDROGENATION OF CYCLOOCTANE BY SUPPORTED NOBLE-METAL CATALYSTS

被引：12

作者：

FUJII, T ^{[1
]}

YUKAWA, K ^{[1
]}

SAITO, Y ^{[1
]}

机构：

[1] UNIV TOKYO, FAC ENGN, DEPT IND CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 03期

关键词：

D O I：

10.1246/bcsj.64.938

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under boiling and refluxing conditions, cyclooctane has been dehydrogenated to cyclooctene and molecular hydrogen selectively with carbon- and alumina-supported Pd, Ph, and Ru catalysts. The activity order among these metal catalysts was Pd > Rh > Ru. The most active carbon-supported Pd catalyst was least sensitive to the rate retardation caused by cyclooctene adsorption. Desorption of molecular hydrogen from the Pd catalyst surface was deduced to proceed rapidly after the rate-determining step.

引用

页码：938 / 941

页数：4

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