CATALYTIC ENANTIOSELECTIVE ALLYLIC OXIDATION

被引：67

作者：

RISPENS, MT ^{[1
]}

ZONDERVAN, C ^{[1
]}

FERINGA, BL ^{[1
]}

机构：

[1] UNIV GRONINGEN,CTR CATALYSIS & SYNTH,DEPT ORGAN & MOLEC INORGAN CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 03期

关键词：

D O I：

10.1016/0957-4166(95)00054-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several chiral Cu(II)-complexes of cyclic amino acids catalyse the enantioselective allylic oxidation of cyclohexene to cyclohexenyl esters. Cyclohexenyl propionate was obtained in 86% yield with e.e.'s up to 61%.

引用

页码：661 / 664

页数：4

共 18 条

[1]

AKERMARK B, 1994, J ORG CHEM, V59, P5729

[2]

Barton D. H. R., 1993, ACTIVATION DIOXYGEN

[3] ALLYLIC OXIDATIONS BY PEROXY ESTERS CATALYZED BY COPPER-SALTS - THE POTENTIAL FOR STEREOSELECTIVE SYNTHESES [J].

BECKWITH, ALJ ;

ZAVITSAS, AA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (26) :8230-8234

[4] STUDY OF COPPER ION CATALYZED REACTIONS OF T-ALKYL PERESTERS WITH SEVERAL OLEFINS [J].

DENNEY, DZ ;

DENNEY, DB ;

APPELBAUM, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (24) :4969-&

[5] BIMETALLIC OXIDATION CATALYSTS - SYNTHESIS, X-RAY-ANALYSIS, AND REACTIVITY OF A BINUCLEAR PARA-HYDROQUINONE-CONTAINING COPPER(II) COMPLEX [J].

GELLING, OJ ;

MEETSMA, A ;

FERINGA, BL .

INORGANIC CHEMISTRY, 1990, 29 (15) :2816-2822

[6]

Henry P. M., 1980, PALLADIUM CATALYZED

[7]

Jacobsen E.N., 1993, CATALYTIC ASYMMETRIC, P159

[8]

JOHNSON RA, 1993, CATALYTIC ASYMMETRIC, P227

[9]

JOHNSON RA, 1993, CATALYTIC ASYMMETRIC, P103

[10] THE 1ST PRACTICAL METHOD FOR ASYMMETRIC EPOXIDATION [J].

KATSUKI, T ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5974-5976

← 1 2 →