THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF MOLYBDENUM OXOMETHOXIDE [MOO(OME)4]2

被引：35

作者：

KESSLER, VG

MIRONOV, AV

TUROVA, NY

YANOVSKY, AI

STRUCHKOV, YT

机构：

[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 117234,RUSSIA

[2] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

POLYHEDRON | 1993年 / 12卷 / 12期

关键词：

D O I：

10.1016/S0277-5387(00)84601-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MoO(OMe)4 has been prepared by anodic oxidation of molybdenum metal in anhydrous methanol containing LiCl as an electrolyte. The X-ray single crystal study showed the complex to consist of pseudo-centrosymmetric dimeric molecules, [MoO(OMe)3(mu-OMe)]2. The general effect of the M(mu-OR)2M ring upon the arrangement of bonds with increased multiplicity is discussed in this and related molecules.

引用

页码：1573 / 1576

页数：4

共 12 条

[1] REACTIONS OF METAL METAL MULTIPLE BONDS .10. REACTIONS OF MO2(OR)6 (M=M) AND [MO(OR)4]X COMPOUNDS WITH MOLECULAR-OXYGEN - PREPARATION AND CHARACTERIZATION OF OXO ALKOXIDES OF MOLYBDENUM - MOO2(OR)2, MOO2(OR)2(BPY), MOO(OR)4, MO3O(OR)10,MO4O8(OR)4(PY)4, AND MO6O10(OR)12
CHISHOLM, MH
FOLTING, K
HUFFMAN, JC
KIRKPATRICK, CC
[J]. INORGANIC CHEMISTRY, 1984, 23 (08) : 1021 - 1037
[2] SOLID-STATE AND SOLUTION STUDIES OF TUNGSTEN(VI) OXOTETRAALKOXIDES
CLEGG, W
ERRINGTON, RJ
KRAXNER, P
REDSHAW, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (08): : 1431 - 1438
[3] Kozlova N. I., 1989, SOV J COORD CHEM, V15, P867
[4] KUCHEIKO SI, 1985, ZH OBSHCH KHIM+, V55, P2396
[5] KUCHEIKO SI, 1985, SOV J COORD CHEM, V11, P867
[6] NIELSON AJ, 1982, POLYHEDRON, V1, P562
[7] CRYSTAL AND MOLECULAR-STRUCTURE OF NIOBIUM PENTAMETHOXIDE - STRUCTURE WITH 2 DIFFERENT CONFORMERS IN UNIT-CELL
PINKERTON, AA
SCHWARZENBACH, D
HUBERTPFALZGRAF, LG
RIESS, JG
[J]. INORGANIC CHEMISTRY, 1976, 15 (05) : 1196 - 1199
[8] Porai-Koshits M. A., 1974, KRISTALLOKHIMIYA STE
[9] SHELDRICK RM, 1990, SHELXTL PC REFERENCE
[10] TUROVA NY, 1990, ZH OBSHCH KHIM+, V60, P113

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