VIBRATIONALLY SELECTIVE AUTOIONIZATION OF PHYSISORBED MOLECULAR NITROGEN

被引:8
作者
BJORNEHOLM, O
NILSSON, A
SANDELL, A
HERNNAS, B
MARTENSSON, N
机构
[1] Department of Physics, Uppsala University, Box 530
来源
PHYSICAL REVIEW B | 1994年 / 49卷 / 03期
关键词
D O I
10.1103/PhysRevB.49.2001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Autoionization from vibrationally resolved core excited states is demonstrated, using nitrogen physisorbed on graphite. The results are compared to photoemission and x-ray absorption, and reveal an adsorption induced elongation of the internuclear separation in the 3 sigma(g)(-1),final state. It is demonstrated that it is only in the case of vibrationally selective excitation that the autoionization final states coincide with the photoemission final states.
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页码:2001 / 2004
页数:4
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