CATALYTIC-OXIDATION OF HYDROCARBONS AND ALCOHOLS BY CARBON-DIOXIDE ON OXIDE CATALYSTS

被引：69

作者：

KRYLOV, OV ^{[1
]}

MAMEDOV, AK ^{[1
]}

MIRZABEKOVA, SR ^{[1
]}

机构：

[1] AZERBAIJAN ACAD SCI,YU G MAMEDALIEV INST PETROCHEM PROC,BAKU 370604,AZERBAIJAN

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1995年 / 34卷 / 02期

关键词：

D O I：

10.1021/ie00041a007

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Reactions of oxidative transformation of organic compounds of different classes (alkanes, alkenes, and alcohols) with a nontraditional oxidant, carbon dioxide, were studied on oxide catalysts Fe-O, Cr-O, Mn-O and on multicomponent systems based on manganese oxide. The supported manganese oxide catalysts are active, selective, and stable in conversion of the CH4 + CO2 mixture into synthesis gas and in oxidative dehydrogenation of C-2-C-7 hydrocarbons and the lower alcohols. Unlike metal catalysts manganese oxide based catalysts do not form a carbon layer during the reaction.

引用

页码：474 / 482

页数：9

共 34 条

[1]

AIKA K, 1988, 9TH P INT C CAT CALG, V2, P907

[2]

ARESTA M, 1986, NATO ASI SERIES C

[3] AN INSITU, ENERGY-DISPERSIVE X-RAY-DIFFRACTION STUDY OF NATURAL-GAS CONVERSION BY CO2 REFORMING [J].

ASHCROFT, AT ;

CHEETHAM, AK ;

JONES, RH ;

NATARAJAN, S ;

THOMAS, JM ;

WALLER, D ;

CLARK, SM .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (13) :3355-3358

[4] PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS-USING CARBON-DIOXIDE [J].

ASHCROFT, AT ;

CHEETHAM, AK ;

GREEN, MLH ;

VERNON, PDF .

NATURE, 1991, 352 (6332) :225-226

[5] OXIDATIVE DEHYDROGENATION OF ETHANE OVER LANTHANA - ACTUAL NATURE OF THE ACTIVE PHASE [J].

BERNAL, S ;

MARTIN, GA ;

MORAL, P ;

PERRICHON, V .

CATALYSIS LETTERS, 1990, 6 (02) :231-238

[6]

BODROV IM, 1967, KINET KATAL, V8, P379

[7] REACTIONS OF CARBON-DIOXIDE WITH CARBON CARBON BOND FORMATION CATALYZED BY TRANSITION-METAL COMPLEXES [J].

BRAUNSTEIN, P ;

MATT, D ;

NOBEL, D .

CHEMICAL REVIEWS, 1988, 88 (05) :747-764

[8]

Breslow G.S., 1981, J CHEM SOC CHEM COMM, V21, P1145

[9] ACTIVATION OF CH4 AND ITS REACTION WITH CO2 OVER SUPPORTED RH CATALYSTS [J].

ERDOHELYI, A ;

CSERENYI, J ;

SOLYMOSI, F .

JOURNAL OF CATALYSIS, 1993, 141 (01) :287-299

[10] BIFUNCTIONAL ACTIVATION OF CARBON-DIOXIDE - SYNTHESIS AND STRUCTURE OF A REVERSIBLE CO2 CARRIER [J].

FACHINETTI, G ;

FLORIANI, C ;

ZANAZZI, PF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (23) :7405-7407

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