ET3N.2HF, A NEW CONVENIENT REAGENT FOR NUCLEOPHILIC FLUORINE DISPLACEMENT-REACTIONS

被引：55

作者：

GIUDICELLI, MB ^{[1
]}

PICQ, D ^{[1
]}

VEYRON, B ^{[1
]}

机构：

[1] UNIV LYON 1,CNRS,CHIM ORGAN LAB 3,43 BD 11 NOVEMBRE,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)97108-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Syntheses of fluoro compounds by nucleophilic substitution of bromides or methanesulfonates using Et3N.2HF as the reagent are reported. The formation of undesired elimination side products is limited. The synthesis of this new fluorinating reagent is also reported. © 1990.

引用

页码：6527 / 6530

页数：4

共 21 条

[1] TETRABUTYLAMMONIUM AND POLYMER-SUPPORTED DIHYDROGENTRIFLUORIDE - NEW HYDROFLUORINATING REAGENTS FOR ELECTROPHILIC ALKYNES
ALBERT, P
COUSSEAU, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) : 961 - 962
[2] ARANDA G, 1965, B SOC CHIM FR, P1890
[3] ARANDA G, 1966, B SOC CHIM FR, P2850
[4] ARANDA G, 1967, THESIS PARIS
[5] TETRABUTYLAMMONIUM BIFLUORIDE - A VERSATILE AND EFFICIENT FLUORINATING AGENT
BOSCH, P
CAMPS, F
CHAMORRO, E
GASOL, V
GUERRERO, A
[J]. TETRAHEDRON LETTERS, 1987, 28 (40) : 4733 - 4736
[6] CAINELLI G, 1976, SYNTHESIS-STUTTGART, P472
[7] ANIONIC ACTIVATION IN POLYMER-SUPPORTED REACTIONS .2. STEREOCHEMICAL STUDIES ON THE INTRODUCTION OF FLUORINE AT CHIRAL CENTERS AND IN BIOLOGICALLY SIGNIFICANT MOLECULES
COLONNA, S
RE, A
GELBARD, G
CESAROTTI, E
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (09): : 2248 - 2252
[8] NUCLEOPHILIC FLUORINE DISPLACEMENT-REACTIONS - A COMPARISON OF REACTIVITIES OF POLYMER-SUPPORTED FLUORIDE AND ACID FLUORIDES P+F-, NHF (N = 0-2)
COUSSEAU, J
ALBERT, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (22) : 5380 - 5383
[9] COUSSEAU J, 1986, B SOC CHIM FR, P910
[10] ISOMERIZATION OF N-PHENYLBUTENES CATALYSED BY PALLADIUM COMPLEXES
DAVIES, NR
DIMICHIE.AD
PICKLES, VA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1968, 21 (02) : 385 - &

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