REDETERMINATION OF THE BETA-CA2P2O7 STRUCTURE

被引：83

作者：

BOUDIN, S

GRANDIN, A

BOREL, MM

LECLAIRE, A

RAVEAU, B

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193005608

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Beta Dicalcium diphosphate is composed of eclipsed P2O7 groups linked through Ca2+ cations. The P-O(b) bonds involving the bridging O atoms are longer [average 1.620 (5) angstrom] than the others [average 1.517 (5) angstrom]. As the 'O4' tetrahedra are almost regular the displacement of the P atoms involves two sets of O-P-O angles: O-P-O congruent-to 112.7 (2) and O-P-O(b) congruent-to 106.0 (2)-degrees.

引用

页码：2062 / 2064

页数：3