SOLID-STATE POLYMERIZATION OF 1,6-DICHLORO-2,4-HEXADIYNE UNDER HIGH-PRESSURE

被引：2

作者：

KATO, J

NAKAMURA, K

机构：

[1] Research Association for Basic Polymer Technology, Minato-ku, Tokyo, 105

[2] Asahi Chemical Industry Co., Ltd., Fibers Development Laboratory, Nobeoka, 882

来源：

KOBUNSHI RONBUNSHU | 1990年 / 47卷 / 01期

关键词：

Diacetylene; High Pressure DTA; Solid State Polymerization; Topochemical; Topotactic;

D O I：

10.1295/koron.47.57

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Solidification and melting behavior of l,6-dichloro-2,4-hexadiyne was studied by high pressure DTA. This compound was found to polymerize under 5000 kg/cm2 at 40°C for 18 h. The polymerization manner was topochemical and topotactic. The polymer has a crystalline structure different from that of a polymer obtained by photopolymeriza-tion in the frozen state. © 1990, The Society of Polymer Science, Japan. All rights reserved.

引用

页码：57 / 61

页数：5