DIENOPHILIC REACTIVITY OF PENTACARBONYL(METHOXYVINYLCARBENE)TUNGSTEN IN (4+2)-CYCLOADDITIONS

被引：16

作者：

ADAM, H ^{[1
]}

ALBRECHT, T ^{[1
]}

SAUER, J ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ORGAN CHEM,D-93040 REGENSBURG,GERMANY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)75837-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The vinyl-methoxy-carbene complex 1 shows dienophilic reactivity comparable to maleic anhydride in (4+2)-cycloadditions. The reactions of 1 with unsymmetrical 1,3-dienes are stereo- and regioselective.

引用

页码：557 / 560

页数：4

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