STERN-GERLACH DEFLECTION SPECTRUM OF CHLORINE DIOXIDE

被引：6

作者：

GEDANKEN, A

KELNER, V

SOMINKSA, E

机构：

[1] Department of Chemistry, Bar-Ilan University, Ramat Gan

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 221卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(94)00246-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Stern-Gerlach magnet deflection spectrum of a molecular beam of OClO cooled by supersonic expansion is spatially resolved only at low pressures. At these pressures two beams separated in space are detected. At higher pressures no deflection is observed. We attribute this behavior to the formation of a diamagnetic dimer.

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页码：274 / 278

页数：5

相关论文

共 22 条

[1] INTRAMOLECULAR SPIN RELAXATION IN ISOLATED MOLECULES [J].

AMIRAV, A ;

NAVON, G .

PHYSICAL REVIEW LETTERS, 1981, 47 (13) :906-909

[2] INTRAMOLECULAR SPIN RELAXATION PROBED BY STERN-GERLACH EXPERIMENTS [J].

AMIRAV, A ;

NAVON, G .

CHEMICAL PHYSICS, 1983, 82 (03) :253-267

[3] COOLING OF LARGE AND HEAVY MOLECULES IN SEEDED SUPERSONIC BEAMS [J].

AMIRAV, A ;

EVEN, U ;

JORTNER, J .

CHEMICAL PHYSICS, 1980, 51 (1-2) :31-42

[4]

[Anonymous], COMMUNICATION

[5] MAGNETIC-PROPERTIES OF FREE COBALT CLUSTERS [J].

BUCHER, JP ;

DOUGLASS, DC ;

BLOOMFIELD, LA .

PHYSICAL REVIEW LETTERS, 1991, 66 (23) :3052-3055

[6] MAGNETIC-BEHAVIOR OF FREE-IRON AND IRON-OXIDE CLUSTERS [J].

COX, DM ;

TREVOR, DJ ;

WHETTEN, RL ;

ROHLFING, EA ;

KALDOR, A .

PHYSICAL REVIEW B, 1985, 32 (11) :7290-7298

[7] ALUMINUM CLUSTERS - MAGNETIC-PROPERTIES [J].

COX, DM ;

TREVOR, DJ ;

WHETTEN, RL ;

ROHLFING, EA ;

KALDOR, A .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (08) :4651-4656

[8] LARGE LOSSES OF TOTAL OZONE IN ANTARCTICA REVEAL SEASONAL CLOX/NOX INTERACTION [J].

FARMAN, JC ;

GARDINER, BG ;

SHANKLIN, JD .

NATURE, 1985, 315 (6016) :207-210

[9] STERN-GERLACH DEFLECTION SPECTRA OF NITROGEN-OXIDE RADICALS [J].

GEDANKEN, A ;

KUEBLER, NA ;

ROBIN, MB ;

HERRICK, DR .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (08) :3981-3993

[10] MAGNETIC DEFLECTION SPECTRUM OF VCL4 [J].

GEDANKEN, A ;

KUEBLER, NA ;

ROBIN, MB ;

HERRICK, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5568-5572