SYNTHESIS OF SELECTIVELY FLUORINATED SUBSTRATES VIA ORGANOMETALLIC REAGENTS DERIVED FROM CF2=CFCL, CF2=CCL2, CF2=CH2

被引：54

作者：

NORMANT, JF

机构：

[1] Laboratoire de Chimie des Organoéléments, Université P. et M. Curie, 75252 Paris Cedex 05, Tour 44-45

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 400卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)83003-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Selectively fluorinated reagents can be prepared via mono- or polyfluorinated vinyl-lithium reagents, obtained from cheap monomers by metal/halogen exchange or metallation. These organolithium reagents can be condensed with various electrophiles, and further rearrangements lead to the regio- and stereo-selective introduction of fluorine into organic molecules. Alternatively, they can be converted into zinc compounds of higher stability.

引用

页码：19 / 34

页数：16

共 51 条

[1] SYNTHESES OF ORGANOFLUORINE COMPOUNDS .8. SOLVOLYTIC RING-OPENING OF ALKOXYCHLOROFLUOROCYCLOPROPANES - READY ACCESS TO FLUORINATED ALPHA-BETA-UNSATURATED ALDEHYDES AND KETONES [J].