HYDROTHERMAL SYNTHESIS OF ELECTRODE MATERIALS - PYROCHLORE TUNGSTEN TRIOXIDE FILM

被引：39

作者：

GUO, JD

LI, YJJ

WHITTINGHAM, MS

机构：

[1] SUNY BINGHAMTON,DEPT CHEM,BINGHAMTON,NY 13902

[2] SUNY BINGHAMTON,MAT RES CTR,BINGHAMTON,NY 13902

[3] IND TECHNOL RES INST,MAT RES LABS,HSINCHU 31015,TAIWAN

来源：

JOURNAL OF POWER SOURCES | 1995年 / 54卷 / 02期

关键词：

TUNGSTEN OXIDES; CATHODES; SYNTHESIS;

D O I：

10.1016/0378-7753(94)02125-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal synthesis methods have been successfully used to prepare new transition-metal oxides for cathodes in electrochemical devices such as lithium batteries and electrochromic windows. The tungsten oxides were the first studied, but the method has been extended to the oxides of molybdenum, vanadium and manganese. Sodium tungsten oxide films with the pyrochlore structure have been prepared on gold/alumina and indium-doped tin oxide substrates. These films reversibly and rapidly intercalate lithium and hydrogen ions.

引用

页码：461 / 464

页数：4

共 18 条

[1]

Basu S., 1979, Fast Ion Transport in Solids. Electrodes and Electrolytes, P149

[2] A NEW TUNGSTEN-OXIDE WITH 3D TUNNELS - WO3 WITH THE PYROCHLORE-TYPE STRUCTURE [J].