DI-MU-CHLORO-BIS[(4-HYDROXY-4'-METHYLAZOBENZENATO-C2,N2)PALLADIUM(II)] ETHANOL SOLVATE

被引：12

作者：

ARMENTANO, S ^{[1
]}

CRISPINI, A ^{[1
]}

DEMUNNO, G ^{[1
]}

GHEDINI, M ^{[1
]}

NEVE, F ^{[1
]}

机构：

[1] UNIV CALABRIA,DIPARTIMENTO CHIM,I-87030 ARCAVACATA,ITALY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270191005188

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C26H22Cl2N4O2Pd2.C2H5OH, M(r) = 752.2, triclinic, P1BAR, a = 9.354 (2), b = 11.926 (3), c = 13.417 (3) angstrom, alpha = 90.30 (2), beta = 105.04 (2), gamma = 93.00 (2)-degrees, V = 1443.3 (6) angstrom 3, Z = 2, D(x) = 1.731 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 14.52 cm-1, F(000) = 748, T = 298 K, R = 0.037 for 4755 reflections with I > 3-sigma(I). The dimeric complex has an overall trans conformation with bridging Cl atoms and a folded Pd2Cl2 unit. The Cl---Cl hinged dihedral angle is 14.0 (1)-degrees. The Pd...Pd distance is 3.554 (1) angstrom.

引用

页码：2545 / 2547

页数：3

共 13 条

[1] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE
APPLETON, TG
CLARK, HC
MANZER, LE
[J]. COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) : 335 - 422
[2] CYCLOPALLADATED COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF DI-MU-CHLORO-BIS[2',6'-DIMETHYLAZOBENZENATO-C2,N2)PALLADIUM(II)]
ARMENTANO, S
CRISPINI, A
DEMUNNO, G
GHEDINI, M
NEVE, F
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 966 - 968
[3] STRUCTURAL SYSTEMATICS OF THE ISOMERIC DI-MU-CHLOROBIS(N,N-DIALKYLBENZYLAMINE-2,C,N)DIPALLADIUM(II) COMPLEXES - THE CRYSTAL-STRUCTURES OF THE ORTHO-METHOXY, META-METHOXY AND PARA-METHOXY SUBSTITUTED COMPLEXES
BARR, N
DYKE, SF
SMITH, G
KENNARD, CHL
MCKEE, V
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 288 (01) : 109 - 117
[4] DI-MU-CHLORO-BIS[(BENZOPHENONE PHENYLHYDRAZONIDO-N,C)PALLADIUM(II)]
CLARK, PW
DYKE, SF
SMITH, G
KENNARD, CHL
WHITE, AH
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 : 1742 - 1745
[5] CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-MU-DICHLORO-BIS(PHENYLAZOPHENYL-2C,N')DIPLATINUM(II)
ELDER, RC
CRUEA, RDP
MORRISON, RF
[J]. INORGANIC CHEMISTRY, 1976, 15 (07) : 1623 - 1626
[6] TRANSITION-METALS COMPLEXED TO ORDERED MESOPHASES .6. SYNTHESIS, MESOMORPHIC BEHAVIOR AND X-RAY MOLECULAR-STRUCTURE OF THE CYCLOPALLADATED DIMER [(L)PDCL]2 (HL=N-(4-METHOXYBENZYLIDENE)-4'-BUTYLANILINE)
GHEDINI, M
ARMENTANO, S
DEMUNNO, G
CRISPINI, A
NEVE, F
[J]. LIQUID CRYSTALS, 1990, 8 (05) : 739 - 744
[7] CARBON-COMPOUNDS OF TRANSITION-METALS .25. CRYSTAL AND MOLECULAR STRUCTURE OF ACETATOBIS(PHENYLAZOPHENYL-2C,N')RHODIUM(II)
HOARE, RJ
MILLS, OS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (19): : 2138 - &
[8] CARBON-COMPOUNDS OF TRANSITION-METALS .26. CRYSTAL AND MOLECULAR STRUCTURE OF DI MU CHLORO-DICARBONYLRHODIUM(I)BIS(PHENYLAZOPHENYL-2C,N')RHODIUM(III)
HOARE, RJ
MILLS, OS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (19): : 2141 - &
[9] PARST - A SYSTEM OF FORTRAN ROUTINES FOR CALCULATING MOLECULAR-STRUCTURE PARAMETERS FROM RESULTS OF CRYSTAL-STRUCTURE ANALYSES
NARDELLI, M
[J]. COMPUTERS & CHEMISTRY, 1983, 7 (03): : 95 - 98
[10] PAULING L, 1960, NATURE CHEM BOND, P00257

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