CHEMICAL-REDUCTION OF LIGATED NITROSYL IN FE2(NO)4(MU-SR)2

被引：10

作者：

CHAU, CN ^{[1
]}

WOJCICKI, A ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

POLYHEDRON | 1992年 / 11卷 / 07期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86022-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of Fe2(NO)4(mu-SR)2(1, R = Me or Et) with two equivalents of sodium dispersion, KH, LiBEt3H or Li- or KB(s-Bu)3H in THF affords [Fe2(NO)4(mu-SR)2]2-; treatment of product solutions with an excess of R'I (R' = Me or Et) yields 1, Fe2(NO)4(mu-I)2 and Fe2(NO)4(mu-SR)(mu-NHR') or Fe2(NO)4(mu-SR)(mu-NHEt) (when the reductant is LiBEt3H).

引用

收藏

页码：851 / 852

页数：2

相关论文

共 8 条

[1]

BOTTOMLEY F, 1989, REACTIONS COORDINATE, V2, P115

[2] NITROSYL COMPLEXES OF IRON SULFUR CLUSTERS [J].

BUTLER, AR ;

GLIDEWELL, C ;

LI, MH .

ADVANCES IN INORGANIC CHEMISTRY, 1988, 32 :335-393

[3] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

[4] (METAL-METAL)-NONBONDING [FE2(CO)6(MU-2-PPH2)2]2-DIANION - SYNTHESIS, STRUCTURAL-ANALYSIS OF ITS UNUSUAL DIMERIC GEOMETRY, AND STEREOCHEMICAL-BONDING IMPLICATIONS [J].

GINSBURG, RE ;

ROTHROCK, RK ;

FINKE, RG ;

COLLMAN, JP ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (22) :6550-6562

[5]

HAYMORE B, 1968, INORG SYNTH, V10, P81

[6] REACTIONS LEADING TO FORMATION AND CLEAVAGE OF METAL METAL AND METAL MU-PHOSPHIDO BONDS IN BINUCLEAR MOLYBDENUM AND TUNGSTEN COMPLEXES - STRUCTURAL-ANALYSES OF W2(CO)8(MU-PPH2)2 AND ITS 2-ELECTRON REDUCTION PRODUCT, [LI(THF)3]2[W2(CO)8(MU-PPH2)2] [J].

SHYU, SG ;

CALLIGARIS, M ;

NARDIN, G ;

WOJCICKI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3617-3625

[7] KINETICS AND MECHANISM OF THE FORMATION OF NITROSOALKANE COMPLEXES BY MIGRATORY INSERTION OF COORDINATED NITRIC-OXIDE INTO COBALT CARBON BONDS [J].

WEINER, WP ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) :3922-3929

[8] REDUCTION CHEMISTRY OF FE2(NO)4(MU-PPH2)2, FE2(NO)4(MU-PCY2)2 AND PROTONATION AND ALKYLATION OF RESULTANT BINUCLEAR IRON NITROSYL ANIONS [J].

YU, YF ;

CHAU, CN ;

WOJCICKI, A .

INORGANIC CHEMISTRY, 1986, 25 (23) :4098-4104