REGIOSELECTIVE DEACETYLATION OF SECONDARY ACETYL ESTERS IN PERACETYLATED METHYL GLUCOPYRANOSIDES BY ASPERGILLUS-NIGER LIPASE

被引：7

作者：

HSIAO, KF

WU, SH

WANG, KT

机构：

[1] ACAD SINICA,INST BIOL CHEM,TAIPEI,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 1993年 / 3卷 / 10期

关键词：

D O I：

10.1016/S0960-894X(01)81030-1

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Peracetylated methyl beta,alpha-D-glucopyranosides (1,2), methyl beta,alpha-D-galactopyranosides (3,4) and methyl alpha-D-mannopyranoside (5) were transformed into the corresponding triacetates with one secondary hydroxyl group and diacetates with two secondary hydroxyl groups by the regioselective hydrolysis of A. niger lipase in 0.1M phosphate buffer/acetone solution.

引用

页码：2125 / 2128

页数：4

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