NEW NEUTRAL NICKEL DITHIOLENE COMPLEXES DERIVED FROM 1,3-DIALKYLIMIDAZOLIDINE-2,4,5-TRITHIONE, SHOWING REMARKABLE NEAR-IR ABSORPTION

被引：57

作者：

BIGOLI, F

DEPLANO, P

DEVILLANOVA, FA

LIPPOLIS, V

LUKES, PJ

MERCURI, ML

PELLINGHELLI, MA

TROGU, EF

机构：

[1] UNIV CAGLIARI,DIPARTIMENTO CHIM & TECNOL INORGAN & MET ORGA,I-09124 CAGLIARI,ITALY

[2] CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,DIPARTIMENTO CHIM GEN & INORGAN ANALIT CHIM FIS,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 03期

关键词：

D O I：

10.1039/c39950000371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis, solution redox properties and electronic spectra of a new series of stable, neutral nickel-dithiolene complexes [Ni(R(2)timdt)(2)] (where R(2)timdt is the monoreduced anion of the first example of 1,3-dialkytimidazolidine-2,4,5-trithione and alkyl = Et, Pr-i, Bu), showing an intense electronic absorption at lambda = 1000 nm, as well as the crystal structure of the Pr-i derivative are reported.

引用

页码：371 / 372

页数：2

共 16 条

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