INTRAMOLECULAR ADDITIONS OF ALLYSILANES TO CONJUGATED DIENONES - A DIRECT STEREOSELECTIVE SYNTHESIS OF (+/-)-14-DEOXYISOAMIJIOL

被引：63

作者：

MAJETICH, G ^{[1
]}

SONG, JS ^{[1
]}

RINGOLD, C ^{[1
]}

NEMETH, GA ^{[1
]}

NEWTON, MG ^{[1
]}

机构：

[1] UNIV TOLEDO, DEPT CHEM, TOLEDO, OH 43606 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 12期

关键词：

D O I：

10.1021/jo00012a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 16-step synthesis of (+/-)-14-deoxyisoamijiol is reported featuring an intramolecular addition of an allylsilane to a conjugated dienone to construct stereospecifically the dolastane skeleton.

引用

页码：3973 / 3988

页数：16

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