CHROMIUM-SUBSTITUTED ALUMINOPHOSPHATE-5 - A RECYCLABLE CATALYST FOR THE SELECTIVE OXIDATION OF SECONDARY ALCOHOLS

被引：86

作者：

CHEN, JD ^{[1
]}

DAKKA, J ^{[1
]}

NEELEMAN, E ^{[1
]}

SHELDON, RA ^{[1
]}

机构：

[1] DELFT UNIV TECHNOL,ORGAN CHEM & CATALYSIS,JULIANALAAN 136,2628 BL DELFT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001379

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Isomorphous substitution of aluminium by chromium in the aluminophosphate-5 framework by hydrothermal synthesis leads to an active, selective and recyclable catalyst for the liquid phase oxidation of secondary alcohols, to the corresponding ketones, using molecular oxygen or tert-butyl hydroperoxide as the terminal oxidant.

引用

页码：1379 / 1380

页数：2

共 12 条

[1]

Cainelli G., 2012, CHROMIUM OXIDATIONS

[2] SELECTIVE OXIDATION OF ALCOHOLS BY CHROMIA-PILLARED - MONTMORILLONITE CATALYST [J].

CHOUDARY, BM ;

DURGAPRASAD, A ;

VALLI, VLK .

TETRAHEDRON LETTERS, 1990, 31 (40) :5785-5788

[3]

Dakka J., 1992, NL Patent, Patent No. 9200968

[4]

FLANIGEN EM, 1989, Patent No. 4759919

[5] SILICOALUMINOPHOSPHATE MOLECULAR-SIEVES - ANOTHER NEW CLASS OF MICROPOROUS CRYSTALLINE INORGANIC SOLIDS [J].

LOK, BM ;

MESSINA, CA ;

PATTON, RL ;

GAJEK, RT ;

CANNAN, TR ;

FLANIGEN, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (20) :6092-6093

[6] CHROMIUM-CATALYZED OXIDATIONS IN ORGANIC-SYNTHESIS [J].

MUZART, J .

CHEMICAL REVIEWS, 1992, 92 (01) :113-140

[7]

Sheldon R. A., 1981, METAL CATALYZED OXID

[8]

SHELDON RA, 1993, TOP CURR CHEM, V164, P21

[9]

SHELDON RA, 1991, CHEMTECH, P566

[10]

WAN BZ, 1991, J CHIN INST CHEM ENG, V22, P17

← 1 2 →