MER, CIS-CHLOROTRIS(DIMETHYLPHENYLPHOSPHINE)NITRIDO(TRIFLUOROMETHYLSULFONATO)RHENIUM(V)

被引：6

作者：

ABRAM, U

WALKER, I

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270195000692

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [ReNCl(CF3SO3)(C8H11P)(3)], is formed by the reaction of [ReNCl2(C8H11P)(3)] with excess trifluoromethanesulfonic acid, The phosphine Ligands are coordinated meridionally. The trifluoromethanesulfonate ligand is in a trans position with respect to the terminal nitrido N atom with an exceptionally long Re-O bond length of 2.403 (5) Angstrom, which is the result of the strong structural trans influence of 'N3-'.

引用

页码：1250 / 1251

页数：2

共 10 条

[1] MIXED-LIGAND COMPLEXES OF RHENIUM .1. THE REACTION OF RENCL2(ME2PHP)3 WITH BIDENTATE CHELATE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF CHLORO-[N-(N,N-DIETHYLTHIOCARBAMOYL)-BENZAMIDINATO]BIS(DIMETHYLPHENYLPHOSPHINE)NITRIDORHENIUM(V), [REN(CL)(ME2PHP)2(ET(2)TCB)], AND (BIS(MU-ETHYLDITHIOPHOSPHATO-S,S',O)DI[BIS(DIMETHYLPHENYLPHOSPHINE)NITRIDORHENIUM(V)]), [REN(ME2PHP)2ETDTP)]2 [J].