SYNTHESIS AND STRUCTURE OF FECL(C=CPH)(DMPE)2

被引：60

作者：

FIELD, LD ^{[1
]}

GEORGE, AV ^{[1
]}

HAMBLEY, TW ^{[1
]}

机构：

[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 22期

关键词：

D O I：

10.1021/ic00347a046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of FeCl2(DMPE)2with phenylacetylene in methanol solution forms three phosphorus-containing products: two complexes, FeCl(C≡CPh)(DMPE)2and [Fe(η3-C(CHPh)C2Ph)(DMPE)2][PF6], and a cyclic diphosphonium salt, [Me2PCHPhCH2P(CH2CH2)Me2] [Cl]2. Crystals of FeCl(C≡CPh)(DMPE)2are monoclinic, space group P21/n, with a = 9.038 (3) Å b = 8.852 (2) Å, ? = 30.675 (9) Å, β = 96.34 (2)°, ? = 4, and R = 0.042 (2262 F values). © 1990, American Chemical Society. All rights reserved.

引用

页码：4565 / 4569

页数：5

共 40 条

[1] DIAMAGNETIC REVERSIBLE PARAMAGNETIC EQUILIBRIA IN SOLUTIONS OF BIS(DIALKYLPHOSPHINO)ETHANE COMPLEXES OF IRON [J].

BAKER, MV ;

FIELD, LD ;

HAMBLEY, TW .

INORGANIC CHEMISTRY, 1988, 27 (16) :2872-2876

[2] FORMATION OF MOLECULAR-HYDROGEN COMPLEXES OF IRON BY THE REVERSIBLE PROTONATION OF IRON DIHYDRIDES WITH ALCOHOLS [J].

BAKER, MV ;

FIELD, LD ;

YOUNG, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (08) :546-548

[3] NEW NICKEL(II), PALLADIUM(II) AND PALLADIUM(0) DERIVATIVES OF PARA-DIETHYNYLBENZENE [J].

BALLESTER, L ;

CANO, M ;

SANTOS, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 229 (01) :101-107

[4]

Barton D., 1979, COMPREHENSIVE ORGANI, V2

[5] CRYSTAL AND MOLECULAR-STRUCTURES OF PARA-PHENYLENE-BIS[ETHYNYLISOTHIOCYANATO-TRANS-BIS(TRIETHYLPHOSPHINE)PLATINUM (II)] [J].

BEHRENS, U ;

HOFFMANN, K ;

KOPF, J ;

MORITZ, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 117 (01) :91-98

[6] CATIONIC LOW-SPIN BIS[1,2-BIS(DIALKYLPHOSPHINO)ETHANE]IRON(II) COMPLEXES [J].

BELLERBY, JM ;

MAYS, MJ ;

SEARS, PL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (13) :1232-1236

[7]

BELLERBY JM, 1976, J ORGANOMET CHEM, V4117, pC21

[8]

BERKE H, 1981, Z NATURFORSCH B, V36, P929

[9]

BRUCE MI, 1983, ADV ORGANOMET CHEM, V22, P59

[10] CONVENIENT SYNTHESIS OF 1,2-BIS(DICHLOROPHOSPHINO)ETHANE, 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE AND 1,2-BIS(DIETHYLPHOSPHINO)ETHANE [J].

BURT, RJ ;

CHATT, J ;

HUSSAIN, W ;

LEIGH, GJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 182 (02) :203-206

← 1 2 3 4 →