OPTICALLY PURE CHIRAL SULFOXIDES USING EPHEDRINE AS A CHIRAL AUXILIARY

被引：39

作者：

BENSON, SC ^{[1
]}

SNYDER, JK ^{[1
]}

机构：

[1] BOSTON UNIV,DEPT CHEM,590 COMMONWEALTH AVE,BOSTON,MA 02215

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期

关键词：

CHIRAL SULFOXIDE; EPHEDRINE; 1,2,3-OXATHIAZOLIDINE-S-OXIDE;

D O I：

10.1016/S0040-4039(00)79417-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically pure chiral sulfoxides can be formed in good to excellent yields by sequential displacement reactions of organometallic reagents on the 1,2,3-oxathiazolidine-S-oxide formed from ephedrine and thionyl chloride, a modification of the Wudl and Lee procedure.

引用

页码：5885 / 5888

页数：4

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