DIPYRIDINIOMETHANE CHLOROPENTAFLUOROOSMATE(IV), [(C5H5N)(2)CH2][OSF5CL]

被引：11

作者：

BRUHN, C

PREETZ, W

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194006633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sublattice of the mixed-ligand complex anions, [OsF5Cl](2-), of the title compound [N,N-methylenepyridinium chloropentafluoroosmate(IV)] is completely ordered. Due to the mutual trans influence in the asymmetric Cl-Os-f axis, the Os-f distance of 1.959 (4) Angstrom is slightly longer in comparison to the average value of 1.919 Angstrom found for the symmetric F-Os-F axes. Accordingly, the Os-Cl distance of 2.329 (2) Angstrom is shortened in relation to that of 2.364 Angstrom in the octahedral complex anion of K-2[OsCl6].

引用

页码：1687 / 1690

页数：4

共 16 条

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