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AN ORDERED WATER MOLECULAR ASSEMBLY STRUCTURE IN A SLIT-SHAPED CARBON NANOSPACE
被引：168
作者：
IIYAMA, T
NISHIKAWA, K
OTOWA, T
KANEKO, K
机构：
[1] CHIBA UNIV,FAC SCI,DEPT CHEM,INAGE KU,CHIBA 263,JAPAN
[2] YOKOHAMA NATL UNIV,FAC EDUC,DEPT CHEM,YOKOHAMA,KANAGAWA 240,JAPAN
[3] KANSAI COKE & CHEM CO LTD,CTR RES & DEV,AMAGASAKI,HYOGO 660,JAPAN
关键词：
D O I：
10.1021/j100025a004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ;
081704 ;
摘要：
The X-ray diffraction of adsorbed water molecules in a slit-shaped carbon nanospace of width 1.4 nm was measured at 303 K. The electron radial distribution function of the adsorbed water showed that the number of nearest-neighbor molecules of the adsorbed Water is less than that of bulk liquid water and that the adsorbed water has a long-range ordered structure compared with bulk liquid water. The results indicate directly:the formation of an ordered assembly structure of water adsorbed in the hydrophobic nanospace.
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页码：10075 / 10076
页数：2
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