METAL-ION RECOGNITION - DONOR-SET CONTROL OF SILVER(I)/LEAD(II) DISCRIMINATION USING MIXED-DONOR MACROCYCLIC LIGANDS

被引:28
作者
ADAM, KR [1 ]
BALDWIN, DS [1 ]
BASHALL, A [1 ]
LINDOY, LF [1 ]
MCPARTLIN, M [1 ]
POWELL, HR [1 ]
机构
[1] POLYTECH N LONDON,DEPT APPL CHEM & LIFE SCI,LONDON N7 8DB,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 02期
关键词
D O I
10.1039/dt9940000237
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The systematic variation of the donor atom set in a dibenzo-substituted, 17-membered ring structure on the ability of the resultant systems to discriminate between silver(I) and lead(ll) has been performed; the compound containing a S2N2S-donor set yielded discrimination of the order of 10(9) in favour of silver(I).
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页码:237 / 238
页数:2
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