IMINYL RADICALS .1. GENERATION AND INTRAMOLECULAR CAPTURE BY AN OLEFIN

被引:51
作者
BOIVIN, J [1 ]
FOUQUET, E [1 ]
ZARD, SZ [1 ]
机构
[1] ECOLE POLYTECH,CNRS,SYNTH ORGAN LAB,F-91128 PALAISEAU,FRANCE
关键词
D O I
10.1016/S0040-4020(01)80849-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Slow addition of tributylstannane to sulphenylimines 2 give the corresponding Delta(1)- pyrrolenines 5 by an intramolecular addition of the intermediate iminyl radical, a process which can be easily coupled to an intermolecular addition to an electrophilic olefin.
引用
收藏
页码:1745 / 1756
页数:12
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