ZINTL IONS AS STRUCTURAL UNITS IN LIQUID ALLOYS

被引：42

作者：

VANDERLUGT, W

机构：

[1] Solid State Physics Laboratory, University of Groningen, Groningen, 9747

来源：

PHYSICA SCRIPTA | 1991年 / T39卷

关键词：

D O I：

10.1088/0031-8949/1991/T39/059

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Anion clustering according to a rule discovered by E. Zintl may occur in ionic alloys. The chemical bonds between the anions are predominantly covalent. The drastic consequences of this effect for the electronic and structural properties of liquid ionic alloys are demonstrated for alloys of alkali metals with Pb, Sn, Bi, Tl and In.

引用

页码：372 / 377

页数：6

共 53 条

[1] DAS VERHALTEN DER ALKALIMETALLE ZU HALBMETALLEN .10. DIE KRISTALLSTRUKTUREN VON KSI, RBSI, CSSI, KGE, RBGE UND CSGE
BUSMANN, E
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1961, 313 (1-2): : 90 - 106
[2] UNIFIED APPROACH FOR MOLECULAR-DYNAMICS AND DENSITY-FUNCTIONAL THEORY
CAR, R
PARRINELLO, M
[J]. PHYSICAL REVIEW LETTERS, 1985, 55 (22) : 2471 - 2474
[3] STRUCTURAL PHASE-STABILITY OF B2 AND B32 INTERMETALLIC COMPOUNDS
CHRISTENSEN, NE
[J]. PHYSICAL REVIEW B, 1985, 32 (01): : 207 - 228
[4] A MODEL FOR THE STRUCTURE OF LIQUID LI4PB
COPESTAKE, AP
EVANS, R
RUPPERSBERG, H
SCHIRMACHER, W
[J]. JOURNAL OF PHYSICS F-METAL PHYSICS, 1983, 13 (10): : 1993 - 2010
[5] LIQUID SEMICONDUCTORS
ENDERBY, JE
BARNES, AC
[J]. REPORTS ON PROGRESS IN PHYSICS, 1990, 53 (02) : 85 - 179
[6] METAL-NON-METAL TRANSITION IN LIQUID ALLOYS WITH POLYVALENT COMPONENTS
FRANZ, JR
BROUERS, F
HOLZHEY, C
[J]. JOURNAL OF PHYSICS F-METAL PHYSICS, 1982, 12 (11): : 2611 - 2623
[7] ABINITIO MOLECULAR-DYNAMICS SIMULATION OF MOLTEN KSI
GALLI, G
PARRINELLO, M
[J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1990, 2 : SA227 - SA231
[8] ELECTRONIC-STRUCTURE AND CHARGE-TRANSFER-INDUCED CLUSTER FORMATION IN ALKALI-GROUP-IV ALLOYS
GEERTSMA, W
DIJKSTRA, J
VANDERLUGT, W
[J]. JOURNAL OF PHYSICS F-METAL PHYSICS, 1984, 14 (08): : 1833 - 1845
[9] THE STABILITY OF SOLID AND LIQUID COMPOUNDS WITH STRONG ANION ANION INTERACTIONS
GEERTSMA, W
[J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1990, 2 (42) : 8517 - 8524
[10] POLYANIONIC CLUSTERS IN LIQUID ALKALI-LEAD COMPOUNDS
HAFNER, J
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 117 : 64 - 67

← 1 2 3 4 5 6 →