OXIDATION TREATMENT OF CARBON WHISKERS FORMED BY PYROLYSIS OF BENZENE IN GAS-PHASE

被引：4

作者：

MATSUMOTO, M ^{[1
]}

HASHIMOTO, T ^{[1
]}

MURATA, K ^{[1
]}

GOTO, S ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT CHEM ENGN,NAGOYA 46401,JAPAN

来源：

KAGAKU KOGAKU RONBUNSHU | 1993年 / 19卷 / 01期

关键词：

OXIDATION; VAPOR-GROWN CARBON FIBER; CARBON WHISKER; BENZENE; CARBON DIOXIDE;

D O I：

10.1252/kakoronbunshu.19.1

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The weight of carbon whiskers formed by pyrolysis of benzene was decreased at a temperature higher than 600-degrees-C by oxidation under air atmosphere. Oxidation of carbon whiskers with carbon dioxide was a reaction of first order and its activation energy was 145 kJ/mol. Oxidation began in the turbostatic layer on the outside of carbon whiskers, and then a ''graphite-like'' domain inside the carbon whiskers was exposed. After oxidation treatment functional groups of ether, carbonyl and lactone were added to the surface of the carbon whiskers.

引用

页码：1 / 6

页数：6

共 11 条

[1] KINETICS OF GRAPHITE OXIDATION [J].