A NOVEL, MILD PALLADIUM-MEDIATED DEPROTECTION OF O-ALLYL AND PROP-1-ENYL ETHERS

被引：60

作者：

MEREYALA, HB

GUNTHA, S

机构：

[1] Indian Institute of Chemical Technology, Hyderabad

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)91833-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild method for the deprotection of diverse 0-allyl (1a-5a) and prop-l-enyl ethers (1d-5d) of glycosides and inositol by use of PdCl2/CuCl/DMF-H2O/02 is described.

引用

页码：6929 / 6930

页数：2

共 12 条

[1] ALCL3-N,N-DIMETHYLANILINE - A NOVEL BENZYL AND ALLYL ETHER CLEAVAGE REAGENT [J].

AKIYAMA, T ;

HIROFUJI, H ;

OZAKI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (07) :1932-1938

[2] CLEAVAGE OF ALLYL ETHERS WITH PD-C [J].

BOSS, R ;

SCHEFFOLD, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (09) :558-559

[3] SELECTIVE CLEAVAGE OF ALLYL ETHERS UNDER MILD CONDITIONS BY TRANSITION-METAL REAGENTS [J].

COREY, EJ ;

SUGGS, JW .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (18) :3224-3224

[4]

CUNNINGHAM J, 1964, TETRAHEDRON LETT, P1191

[5] SMCL3-CATALYZED ELECTROCHEMICAL CLEAVAGE OF ALLYL ETHERS [J].

ESPANET, B ;

DUNACH, E ;

PERICHON, J .

TETRAHEDRON LETTERS, 1992, 33 (18) :2485-2488

[6] ALLYL ETHER AS A PROTECTING GROUP IN CARBOHYDRATE CHEMISTRY - ISOMERIZATIONS WITH TRISTRIPHENYLPHOSPHINERHODIUM(I) CHLORIDE [J].

GENT, PA ;

GIGG, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (07) :277-278

[7] ALLYL ETHER AS A PROTECTING GROUP IN CARBONHYDRATE CHEMISTRY .2. [J].

GIGG, R ;

WARREN, CD .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (15) :1903-&

[8]

KARIYONE K, 1970, TETRAHEDRON LETT, V34, P2885

[9]

NAKAYAMA K, 1992, CHEM PHARM BULL, V40, P1718

[10] IODINE AS A REAGENT FOR THE READY HYDROLYSIS OF PROP-1-ENYL GLYCOSIDES, OR THEIR CONVERSION INTO OXAZOLINES [J].

NASHED, MA ;

ANDERSON, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (21) :1274-1276

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