Catalytic asymmetric synthesis of binaphthol derivatives by aerobic oxidative coupling of 3-hydroxy-2-naphthoates with chiral diamine-copper complex

被引：95

作者：

Nakajima, M

Kanayama, K

Miyoshi, I

Hashimoto, S

机构：

[1] Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 52期

关键词：

D O I：

10.1016/0040-4039(95)02063-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric aerobic oxidative coupling of 3-hydroxy-2-naphthoate with a copper complex prepared in situ from chiral diamine 3 and cuprous chloride as catalyst afforded binaphthol derivatives in good enantioselectivities up to 73% ee.

引用

页码：9519 / 9520

页数：2

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