[MEO(CH2CH2O)(3)(CH2)(3)C(5)ME(4)]FECL - A HALFSANDWICH IRON(II) CHLORIDE COMPLEX OF REMARKABLE STABILITY

被引：16

作者：

SIEMELING, U

机构：

[1] Fakultät für Chemie, Universität Bielefeld, Bielefeld, D-33615

来源：

CHEMISCHE BERICHTE | 1995年 / 128卷 / 11期

关键词：

HEMILABILE LIGANDS; CYCLOPENTADIENYL LIGANDS; FUNCTIONALIZED; IRON COMPOUNDS; HALFSANDWICH COMPLEX;

D O I：

10.1002/cber.19951281113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of iron(II) chloride with one equivalent of [MeO-(CH2CH2O)(3)(CH2)(3)C(5)Me]Li in THF yields the title halfsandwich complex 1, which is stable in solution up to room temperature. Compound 1 reacts with C5H5Li and CO to give [MeO(CH2CH2O)(3)(CH2)(3)C(5)Me(4)]Fe(C5H5) (2) and [MeO-(CH2CH2O)(3)(CH2)(3)C(5)Me(4)]Fe(CO)(2)Cl (3), respectively in high yields.

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页码：1135 / 1136

页数：2

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