UNUSUAL [2+2] TOPOCHEMICAL CYCLOADDITIONS OF 3-CYANO-CINNAMIC AND 4-CYANO-CINNAMIC ACIDS - TEMPERATURE-DEPENDENT SOLID-STATE PHOTOCHEMICAL-REACTIONS

被引：31

作者：

DHURJATI, MSK

SARMA, JARP ^{[1
]}

DESIRAJU, GR

机构：

[1] INDIAN INST CHEM TECHNOL,DIV INORGAN & PHYS CHEM,HYDERABAD 500007,INDIA

[2] UNIV HYDERABAD,SCH CHEM,HYDERABAD 500134,ANDHRA PRADESH,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The seeming difference in the topochemical [2 + 2] photoreactivity of 3-cyanocinnamic acid 1 and 4-cyanocinnamic acid 2 is caused by differing degrees of ease of molecular motion in the crystals and the unreactive 1 becomes reactive when heated to 130-degrees-C.

引用

页码：1702 / 1703

页数：2

共 6 条

[1] KINETIC FEATURES OF TOPOCHEMICAL PROCESSES OF OLEFIN CRYSTALS [J].