THE SYNTHESIS, STRUCTURAL CHARACTERIZATION AND VARIABLE-TEMPERATURE H-1-NMR STUDY OF THE BIS-TOLUENE HEXARUTHENIUM CARBIDOCARBONYL CLUSTER [RU6C(CO)(11)(ETA(6)-C(6)H(5)ME)(MU(3)-ETA(2)ETA(2)ETA(2)-C(6)H(5)ME)]

被引：21

作者：

BRAGA, D

GREPIONI, F

PARISINI, E

DYSON, PJ

JOHNSON, BFG

REED, D

SHEPHERD, DS

BAILEY, PJ

LEWIS, J

机构：

[1] DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 462卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83371-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, chemical characterisation and single crystal X-ray structural study of the bis-toluene hexaruthenium carbidocarbonyl cluster [Ru6C(CO)(1)1(eta(6)-C(6)H(5)Me)(mu(3)-eta(2):eta(2):eta(2)-C(6)H(5)Me)] is reported. A variable temperature H-1 n.m.r. study reveals that in solution the complex exists in two isomeric forms, one of them, that observed in the solid state and the solid state and the other the trans-[Ru6C(CO)(1)1(eta(6)-C(6)H(5)Me)(2)] isomer. Interchange of the toluene ligand between the mu(3)-eta(2):eta(2):eta(2) and eta(6) co-ordination mode if confirmed by deuterum labelling experiments involving C6D5CD3.

引用

页码：301 / 308

页数：8

共 10 条

[1] ADAMS RD, 1992, POLYHEDRON, V21, P23
[2] STATIC AND DYNAMIC STRUCTURE OF RU3(CO)9(MU-3-ETA-2-ETA-2-ETA-2-C6H6) AT ROOM-TEMPERATURE AND 193-K
BRAGA, D
GREPIONI, F
JOHNSON, BFG
LEWIS, J
HOUSECROFT, CE
MARTINELLI, M
[J]. ORGANOMETALLICS, 1991, 10 (05) : 1260 - 1268
[3] SYNTHESIS OF HEXARUTHENIUM BIS(ARENE) CLUSTERS - MOLECULAR AND CRYSTAL-STRUCTURE OF [RU6C(CO)11(ETA-6-1,3,5-C6H3ME3)(ETA-6-C6H6)] AND [RU6C(CO)11(ETA-6-1,3,5-C6H3ME3)2]
BRAGA, D
GREPIONI, F
RIGHI, S
DYSON, PJ
JOHNSON, BFG
BAILEY, PJ
LEWIS, J
[J]. ORGANOMETALLICS, 1992, 11 (12) : 4042 - 4048
[4] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF DIENE AND BENZENE PENTARUTHENIUM CLUSTERS
BRAGA, D
GREPIONI, F
SABATINO, P
DYSON, PJ
JOHNSON, BFG
LEWIS, J
BAILEY, PJ
RAITHBY, PR
STALKE, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (06): : 985 - 992
[5] HEXANUCLEAR ARENE CLUSTERS OF RUTHENIUM
DYSON, PJ
JOHNSON, BFG
REED, D
BRAGA, D
GREPIONI, F
PARISINI, E
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (18): : 2817 - 2825
[6] A FACE-CAPPING BONDING MODE FOR BENZENE IN TRIOSMIUM CARBONYL CLUSTER COMPLEXES
GALLOP, MA
GOMEZSAL, MP
HOUSECROFT, CE
JOHNSON, BFG
LEWIS, J
OWEN, SM
RAITHBY, PR
WRIGHT, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (07) : 2502 - 2509
[7] BENZENE IN A NEW FACE-CAPPING BONDING MODE - MOLECULAR-STRUCTURES OF [RU6C(CO)11(MU-3-ETA-2-ETA-2-ETA-2-C6H6)(ETA-6-C6H6)] AND [OS3(CO)9(MU-3-ETA-2-ETA-2-ETA-2-C6H6)]
GOMEZSAL, MP
JOHNSON, BFG
LEWIS, J
RAITHBY, PR
WRIGHT, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (23) : 1682 - 1684
[8] Johnson B. F. G., 1968, INORG PHYS THEOR, P2865
[9] Sheldrick G.M., 1986, SHELX86 PROGRAM SOLU
[10] SHELDRICK GM, 1992, SHELX92 PROGRAM CRYS

← 1 →